The classification of hydrocarbons is generally based on the shape of the carbon chain and the type of bond. Based on the carbon chain, hydrocarbons are classified into aliphatic, alicyclic, and aromatic hydrocarbons. Alficial hydrocarbons are open chain hydrocarbons, while alicyclic and aromatic hydrocarbons have a ring chain. The circular chain of aromatic hydrocarbons binds to conjugates, single and double bonds arranged in alternating tubes. An example is benzene All cyclic hydrocarbons that do not belong to the aromatic are classified into alicyclic hydrocarbons. Alicyclic and aromatic hydrocarbons have different properties of properties. The properties of alicyclic hydrocarbons are more similar to aliphatic hydrocarbons. The name of the alisklik states the existence of a chain of circumference but it resembles an aliphatic compound.
Based on the type of bond between the carbon atoms, the hydrocarbons are distinguished by saturation and unsaturation. If all carbon-carbon bonds are single bonds (-C-C-), they are classified as saturated hydrocarbons. If there is one double bond (-C = C-) or triple bond (-C C-), it is called an unsaturated bond
ALKANA
Is a hydrocarbon whose C chain comprises only a single covalent bond. Often referred to as saturated hydrocarbons ... because the number of Hydrogen atoms in each molecule is maximized. Understanding the Alkana nomenclature is vital, as it forms the basis for naming other carbon compounds.
The properties of Alkana
Saturated hydrocarbons (no atoms C bonded so that the number of atoms H maximum)
Called paraffin because small affinity (a bit of joining force)
Hard to react
The Alkane form with C1 - C4 chain at room temperature is gas, C4 - C17 at temperature is liquid and> C18 at room temperature is solid
The boiling point is higher when the C element increases ... and if the number of C atoms is equal then the branching has a lower boiling point
Solubility: soluble in non-polar solvents
The mass of its kind rises as the number of C elements increases
It is a major source of natural gas and petroleum (petroleum)
The formula is generally CnH2n + 2
The homologous sequence of alkanes
Homologous sequence is a group of carbon compounds of the same general formula having similar properties and between successive tribes having different CH2 or in other words an open chain with no branches or with branches with the same branch number.
Properties of homologous alkanes:
O Have similar chemical properties
O Have the same general formula
O Mr. difference between 2 successive tribes of 14
O The longer the carbon chain, the higher the boiling point
N Name Formulas
1 CH4 methane
2 C2H6 ethane
3 C3H8 propane
4 C4H10 butane
5 C5H12 pentane
6 C6H14 hexane
7 C7H16 heptana
8 C8H18 octane
9. C9H20 nonana
10. C10H22 decana
11. C11H24 undekana
12. C12H26 dodecane
TATA NAME ALKANA
1. The alkana name is based on the longest C chain as the main chain. If there are two or more longest chains then selected the largest number of branches
2. A branch is a chain C bound to the main chain. In front of the name alkananya written number and branch name. The name of the branch corresponds to the alkane name by replacing the suffix ana with the suffix il (alkyl).
3. If there are multiple branches of the same, then the name of the branch whose C number is the same is mentioned once but is supplemented with a prefix denoting the total number of branches. The atomic number C to which the bound branches should be written is the number of branches (number of numbers written = prefix used), ie at = 2, tri = 3, tetra = 4, penta = 5 and so on.
4. For branches whose number of C is different sorted in alphabetical order (ethyl first of methyl).
5. The branch number is calculated from the end of the main chain closest to the branch. If the location of the branch closest to both equals starts from:
• Branches that have their alphabetical order first (ethyl first from methyl)
• A larger number of branches (two branches from one branch)
Example:
What is the hydrocarbon name below?
The first time we define the main chain. The main chain is the longest chain:4
The main chain is the one in the red box ...... Why ?? Try to note the left side, if the main chain is straight (the line drops) then sama2 will add 2 C atoms but will only cause one branch (the part that turns down) .... while when we turn down will arise 2 branches (Rule number 1). Now try to look at the right, the explanation is easier .... If the main chain is straight (the line drops) only increase one atom C while when turning down it will increase 2 atom C. So the chain of the main chain it can be turned and not have to Straight and still in a continuous series without branches.
The remaining carbon chain of the main chain is the branch
5
Seen there are 3 branches namely 1 ethyl and 2 methyl. Numbering branch we choose the smallest number:
• when from the left end of the main chain the ethyl is located at the C atom of the main chain of number 3 and methyl is located at the C atoms of the main chain of numbers 2 and 6
• when from the right end of the main chain the ethyl is located at the C atoms of the main chain chain 6 and methyl at the C atoms of the main chain of numbers 3 and 7
The conclusion we sort from the left end.
Naming order: branch number - branch name - the name of the parent chain
So its name: 3 ethyl 2,6 dimethyl octane
The ethyl branch is first called methyl because of its first name alphabet (first "e" from "m"). Because the methyl branch there are two then simply called once plus the prefix "di" which means "two". Because the main chain consists of 8 atoms C then the main chain is named: octane.
Use alkana, as:
• Fuel eg LPG, kerosene, gasoline, and diesel fuel
• Solvent. Various types of hydrocarbons, such as petroleum ether and naphtha, are used as a solvent in the industry and dry cleaning (dry cleaning)
• Hydrogen source. Natural gas and petroleum gas are sources of hydrogen in industries such as ammonia and fertilizer industries
• Lubricants. Lubricants are high-alkane tribes (the number of carbon atoms per molecule is large enough, for example
• Raw materials for other organic compounds. Petroleum and natural gas are the main raw materials for the synthesis of various organic compounds such as alcohol, vinegar and others.
• Industry raw materials. Various industrial products such as plastics, detergents, synthetic rubbers, hair oils, and liniment made from petroleum or natural gas
ALKENA
Is an unsaturated hydrocarbon compound having 1 double bond (-C = C-)
Alkene Properties
Unsaturated hydrocarbon double bond
Alkene is also called olefin (oil forming)
The physiological properties are more active (as sleeping pills -> 2-methyl-2-butene)
The nature is the same as Alkana, but more reactive
Properties: colorless gas, can be burned, distinctive odor, explosive in air (at concentrations 3 - 34%)
Available in regular coal gas in the process of "cracking"
The formula is generally CnH2n
N Formulas Name Molecular Formulas
2 C2H4 ethene CH2 = CH2
3 C3H6 propene CH2 = CH-CH3
4 C4H8 1-butene CH2 = CH-CH2-CH3
4 C4H8 2-butene CH3-CH = CH-CH3
TATA NAME ALKENA
Almost the same as naming Alkana with the difference:
The main chain should contain the double bond and the longest selected. The name of the main chain also resembles the alkane by replacing the suffix -ana with -ena. So the selection of the longest C chain of atoms starts from C duplicated to the right and left and is selected to the right and left of the longest.
The position number of the double bond is written in front of the name of the main chain and is calculated from the tip to the position of the double bond of the smallest serial number C.
The sequence of the branch position number is the same as the sequence numbering of the main chain branch.
Example:
6
Has a major chain ......
7
The calculation of the C atoms in the main chain starts from the double bond ... to the left of the double bond there is only one option while the right double bond there are two choices that are straight and the first turn down .... both equally add 4 C atoms but when the first turn down just produces One branch whereas if straight cause two branches.
So the name is: 3 ethyl 4 methyl 1 pentena
1 pentena can be replaced with n-pentene or special double bond at number one may not be written .... So its name is enough: pentena. Branch number is sorted with the sequence of double bond number. On the above problem from the right end ....
Use of Alkene as:
Can be used as an anesthetic (mixed with O2)
To cook fruits
Plastic industry raw materials, synthetic rubber, and alcohol.
ALKUNA
Is a non-gene hydrocarbon compound Uh which has 1 double bond (-C≡C-). Its properties are similar to Alkene but more reactive. The formula is generally CnH2n-2n Formula Name Molecular formula C2H2 etuna CH≡CH3 C3H4 propuna CH≡C-CH34 C4H6 1-butuna CH≡C-CH2-CH3 Its name is also the same as Alkene, but Suffix -ena replaced -una Usefulness of Alkuna as: etuna (acetylene = C2H2) used for welding iron and steel. For the illumination of the synthesis of other compounds.
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